Abstract
. Тhе development of synthetic organic chemistry is always determined bу creating of new compounds and application in medicine (pharmaceutics), production of cleaning, cosmetic remedies and nutrient additives. The production and application of such compounds are of minimum harm for people and environment regarding to special toxicological and sanitary requirements are concerned. However, multi-tonnage production of lacquers, dyes, rubber, pesticides, disinfectors, plastics, mineral and synthetic lubricants and their stabilizers, industrial surfactants and detergents, fluorocarbons, organometallic compounds make a great harm to environment. In this article the physico-chemical and toxicological characteristics of the most important persistent organic pollutants (РОР) have been described. The possible approaches and technologies of РОР disposal have bееn considered іn the framework of Stockholm Convention.
Research show that when determining the most appropriate method of POPs detoxification, it is necessary to take into account, in addition to technological, some more economic and social factors, pay attention to ensuring human health.
References
Mel'nikov N. N. Pestitsidy. Khimiya, tekhnologiya i primenenie. Khimiya, Moscow, 1987, 712.
Oshina L. A. Promyshlennye khlororganicheskie produkty. Spravochnik. Khimiya, Moscow, 1978, 656.
Bespamyatnov G. P., Krotov Yu. A. Predelno dopustimye kontsentratsii khimicheskikh veshchestv vokruzhayushchey srede. Spravochnik. Khimiya, Leningrad, 1985, 528.
Knunyants I. L. Kratkaya khimicheskaya entsiklopediya. Sov. entsikl., Moscow, 1967, T.5, 1184.
Izmerov N. F., Sanotskiy I. V., Sidorov K. K. Parametry toksikometrii promyshlennykh yadov pri odnokratnom vozdeystvii. Spravochnik. Meditsina, Moscow, 1977, 240.
Zanaveskin L. N., Aver'yanov V. A. Polikhlorbifenily: problemy zagryazneniya okruzhayushchey sredy i tekhnologicheskie metody obezvrezhivaniya. Uspekhi khimii, 1998, 67(8), 788–800.
Fedorov L. A. Dioksiny kak ekologicheskaya opasnost': retrospektiva i perspektivy. Nauka, Moscow, 1993, 266.
Cantoni C., Fabbris F., Rogledi S. Pesticidi organoclorati in caruidi suino. Ind. Alim., 1989, 28(268), 117–118.
Sasaki Kumiko, lshizaka Takashi. Accumulation levels of organochlorine pesticides in human adipose tissue and blood. Bull. Environ contam. and Toxicol, 1991, 46(5), 662–669.
Nishimura Keiichiro, Hirayama Keiko. Quantitative structure-activity relationships of insecticidal diphenyldichlorocyclopropanes. Pestic. Biochem. and Physiol., 1986, 25(2), 153–162.
Valueva L. N., Zatsepin V. M., Promonenkov V. K. Primenenie matematicheskikh metodov dlya analiza svyazi molekulyarnaya struktura pestitsidnaya aktivnost' (chast' 2). Obzor, inf. Ser. "Khimicheskie sredstva zashchity rasteniy". NIITEKhIM, Moskva, 1986, 54.
Zatsepin V. M., Nigmatullin R. S. Informatsionno-vychislitel'nye sistemy v nauchnykh issledovaniyakh po razrabotke pestitsidov. NIITEKhIM, Moskva, 1988, 86.
Dolotovskaya L. Z. and Krut'kov V. M.: Sozdanie perspekt. pestitsidov i syr'ya dlya ikh pr-va, Russia, Ufa 1989, 62
Paasivirta Jaakko. Application of structural organic chemical ecotoxicology. Ann acad. sci. fenn. Ser A2, 1990, 227, 13–26.
Koval' I. V.: Novye formy, vidy, modifikatsii sery i sernoy produktsii, Ukraine, Cherkassy, 1988, 84.
Tsunoda Kunio. Effect of alkyl chain length on the fungicidal efficacy of tertiary amine acetates. J. Antibact. and Antifungal Agents, 1988, 16(11), 515–518.
Tor P. Schultz, Tom F. Hubbard Jr., LeHong Jin, Thomas H. Fisher, Darrel D. Nicholas. Role of stilbenes in the natural durability of wood: Fungicidal structure-activity relationships. Phytochemistry, 1990, 29(5), 1501–1507.
Tomoko Sotomatsu, Yoshiaki Nakagawa, Toshio Fujita. Quantitative structure-activity studies of benzoylphenylurea larvicides: IV. Benzoyl Ortho substituent effects and molecular conformation. Pesticide Biochemistry and Physiology, 1987, 27(2), 156–164.
Andriollo Nunzio, Barino Luisa. QSAR studies of new N-aroyl-N'-arylureas. Lipophilicity and geometrical features as keys for biological activity. Gazz. Chim Ital., 1992, 122(7), 253–259.
Osamu Kirino, Chiyozo Takayama, Satoru Inoue. Quantitative Structure-activity Relationships of the Fungicidal N-Benzylacylamides. Journal of Pesticide Science, 1987, 12(1), 79–84.
Tyurina L. A., Ayupova A. T., Gaskarova A. V., Shevchenko O. K., Lalust'yan G. G. K voprosu o vozmozhnosti komp'yuternogo vyyavleniya svyazi defoliruyushchey aktivnosti so stroeniem khimicheskikh soedineniy. Agrokhimiya, 1990, 3, 118–123.
Rao P.S.C., Wagenet R. J. Spatial Variability of Pesticides in Field Soils: Methods for Data Analysis and Consequences. Weed Science, 1985, 33(suppl. 2), 18–24.
Yousef A. Madhum, Virgil H. Freed. Degradation of the herbicides bromacil, diuron and chlortoluron in soil. Chemosphere, 1987, 16(5), 1003–1011.
Kovacs-Huber G. Environmental degradation of phosmethylan by model experiments. Hung. J. Ind. Chem, 1985, 13(4), 440–455.
Mel'nikov N. N., Arronova N. I. Metabolizm novykh pestitsidov v rasteniyakh i zhivotnykh. Arrokhimiya, 1991, 7, 127–138.
Tomkins David F. Pesticide Formulations: Organohalogen Insecticides; Other Insecticides, Synergists, and Repellents. Journal of Association of Official Analytical Chemists, 1989, 72(1), 63–64.
Mueske W. Separation and purification of pesticide metabolites. Progr. Pestic. Biochem. and Toxicol., 1983, 3, 279–366.
Virlyn W. Burse, Susan L. Head, Margaret P. Korver, Patricia C. McClure, John F. Donahue, Larry L. Needham. Determination of Selected Organochlorine Pesticides and Polychlorinated Biphenyls in Human Serum. Journal of Analytical Toxicology, 1990, 14(3), 137–142.
Różański Lech. Metabolizm, degradacja i toksyczność pestycydów. I. Insektycydy fosforoorganiczne. Wiad. Chem., 1984, 38(10-12), 949–979.
Różański Lech. Metabolizm, degradacja i toksyczność pestycydów. IІ. Insektycydy Karbaminianowe. Wiad. Chem., 1985, 39(3-4), 225–243.
Baillie A. C.: Recent Advances in the Chemistry of Insect Control, United Kingdoom, London, 1985, 25
Ranskiy A. P. Kompleksnyy podkhod k pererabotke i utilizatsii otkhodov razlichnykh promyshlennykh predpriyatiy. Metallurgicheskaya i gornodobyvayushchaya promyshlennost', 1999, 2–3, 95–97.
Ranskiy A. P.: Patent Ukraïny 34805 A. Opubl. 15.03.2001.
Petruk V. G., Yavors'ka O. H., Vasyl'kivs'kyy I. V., Hrynyuk I. I., Ishchenko A. S., Yevsyeyeva M. V., Zvenyhorods'kyy E. L., Petruk H. D., Gordienko O. A., Zvuzdets'ka N. S., Denzanov H. O., Khimicheva H. I. Suchasni ekolohichno chysti tekhnolohiyi znezarazhennya ne-prydatnykh pestytsydiv. Monohrafiya. UNIVERSUM-Vinnytsya, Vinnytsya, 2003, 254.
Petruk V. G., Yavors'ka O. H., Ranskiy A. P., Vasyl'kivs'kyy I. V., Ishchenko V. A., Petruk H. D., Kvaternyuk S. M., Petruk R. V., Tkhor I. I., Turchyk P. M. Ekolohichni aspekty termichnoho zneshkodzhennya neprydatnykh otrutokhimikativ. Monohrafiya. UNIVERSUM-Vinnytsya, Vinnytsya, 2006, 254.
Cherp O. M., Vinichenko V. N. Problema tverdykh bytovykh otkhodov: kompleksnyy podkhod. Ekolayn, Moskva, 1996, 48.
Grechko A. V., Denisenko V. F. Reshenie problemy tverdykh bytovykh otkhodov na osnove poslednikh razrabotok v pirometallurgii. Tsvetnye metally, 1996, 4, 50–52.
Ranskiy A. P., Haydidey O. V., Sandomyrs'kyy O. V., Avdiyenko T. M. Utylizatsiya pestytsydu TKhAN. Fotometrychnyy metod kontrolyu. Khimichna promyslovist' Ukrayiny, 2004, 1, 50–52.
Ranskiy A. P., Sandomyrs'kyy O. V., Kuchuk M. V., Avdiyenko T. M. Utylizatsiya pestytsydu Fentiuram. Khromatohrafichnyy metod kontrolyu. Khimichna promyslovist' Ukrayiny, 2004, 2, 52–55.
Dzhessi L. B., Kingston G. M. Probopodgotovka v mikrovolnovykh pechakh: Teoriya i praktika, Mir. Moskva, 1991, 336.
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